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International Journal of Recent Trends in Science and Technology, ISSN 2277-2812 E-ISSN: 2249-8109
Volume 9, Issue 3, January 2014 pp 315-317
Phenylarsenic(III) Derivatives of Schiff Bases; Synthesis and Characterization
Rita Gupta1, Jyoti Sharma1, Mudit Kumar Gupta2, YashPal Singh1
1Department of Chemistry, University of Rajasthan, Jaipur-302 004, Rajasthan, INDIA.
2L. B. S. College, Jaipur, Rajasthan, INDIA.
Academic Editor : Dr. Aher K.R.
Complexes having the general formula Ph As [ OC (R) CHC(R') NC6H5]n CI2-n[ where n=1 or 2; R=R' =CH3, C6H5; R=CH3, R'=C6H5] have been synthesized by the reactions of phenyl arsenic(III) dichloride with the sodium salts of [RC(O) CHC (R') N(C6H5)]- Na+ in 1:1 and 1:2 molar ratios in anhydrous benzene. These compounds have been characterized by elemental analyses; molecular weight determinations and their tentative structure have been proposed on the basis of spectral (1.R, 1H and 13C NMR) studies.